Tuesday, 10 March 2015

4b) Energetics


Exothermic reactions:
Energy is transferred from the reacting mixture to the surroundings and temperature of surroundings increases

Endothermic:
Energy is transferred from the surroundings to the reaction mixture and temperature of surroundings decreases

Copper cup experiment is a simple calorimetry experiment:

Paper Two - Molar Enthalpy:
Measure temperature change of the experiment
Then use this calculation - Energy, Q = mc∆T                  m= mass of surroundings (water or solution) ∆T = change in temp.
                                           or
                                           ∆H = Q/n                                  n = number of moles    sign - exo and + endo 

∆H is the change in heat energy 
Q is measured in Joules 

Simple Energy Level Diagram:

Exothermic
Energy diagram for an exothermic reaction

Endothermic 
Energy diagram for an endothermic reaction

Ea or activation energy is needed to break or make bonds

Bonds:
Breaking bonds puts energy in - endothermic, 
whilst making new bonds releases energy - exothermic

Paper Two - Using average bond energies to calculate the enthalpy change during a simple chemical equation:

You are given the reaction and table of data 
Then with the information work out the broken bonds (A) and the bonds you make (B)  
Then subtract them to get the ∆H 

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